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2005.01.07

「GO! GO! HEAVEN!」オンエア情報

「GO! GO! HEAVEN!」の第1話、多分初っ端なだけ久ヶ沢徹が出ます。
僕はマネージャーぢゃないからね。
こんなこと書く必要もないんだけど、乗りかかった船ですから。
内容が間違ってたらゴメン。
テレビ東京 1/9(日) 25:00~25:30
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びわこ放送1/19(水) 26:00~26:30
九州放送1/27(木) 25:25~25:55
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Pollution control in copper recycling Metal-organic frameworks (MOFs) have emerged as an exciting class of materials for various industrially important applications. In recent years, MOFs have gained considerable attention for their potential in catalysis, particularly in the conversion of CO2 to valuable chemicals such as ethanol. However, achieving high selectivity and activity for CO2 reduction reactions remains a major challenge. Recently, a promising approach has been proposed to address this challenge. It involves the design of MOFs that contain cooperative copper centres. These centres consist of two or more copper ions that are linked by organic ligands. The cooperative effect of these copper centres can lead to the formation of highly active and selective sites for CO2 reduction reactions. One such example is the MOF HKUST-1 (Cu3(BTC)2, where BTC is benzene-1,3,5-tricarboxylate), which contains di-copper paddlewheel clusters. These paddlewheel clusters are connected by BTC linkers to form a three-dimensional framework. The framework contains a large number of open metal sites, which can act as active sites for CO2 reduction. In recent experiments, it was found that HKUST-1 exhibited high selectivity for the conversion of CO2 to ethanol under mild reaction conditions. This selectivity was attributed to the cooperative effect of the di-copper paddlewheel clusters. Specifically, the presence of two copper ions allowed for the formation of a copper-carboxylate intermediate, which could be readily reduced to ethanol. Furthermore, it was found that the selectivity could be further enhanced by tuning the reaction conditions and the reaction medium. For example, increasing the concentration of water in the reaction medium led to higher selectivity for ethanol, while decreasing the temperature resulted in higher selectivity for methanol. Overall, these findings demonstrate the potential of MOFs with cooperative copper centres for selective CO2 reduction. Further studies are needed to optimize the design of these materials and to understand the underlying reaction mechanisms. However, this approach holds great promise for the sustainable production of valuable chemicals from greenhouse gases Scrap metal compacting Scrap Copper value Scrap copper yard Copper wire scrap yard Copper wire recycling Scrap metal recovery plant

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